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Research in the Walters Gr= oup An Overview
3/1/06 = SAACS Meeting
3DLine
NKU
CHEM
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What’s Our Goal?
To synthesize new supramolecular building blocks and explore their = ph= otochemistry.
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What is Supramolecular Chemistry?
<= span class=3DBB style=3D'position:absolute;left:-3.88%;top:.3em'>nMaking= new “super molecules” by assembling known molecules together
nSupramo= lecular concept allows us to build up a “toolbox” of small molecul= es for use in new systems
<= span class=3DB1B style=3D'position:absolute;left:-4.01%;top:.49em'>nNo n= eed to “reinvent the wheel” each time
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What is Photochemistry?
<= span class=3DBB style=3D'position:absolute;left:-3.77%;top:.3em'>nThe st= udy of the interaction of light (visible and UV radiation) with molecules
nNearly= all interactions of molecules with light produces the transfer of charge from one portion of the molecule to another <= /div>
<= span class=3DB1B style=3D'position:absolute;left:-4.01%;top:.49em'>nIn supramolecular chemistry, from one small molecule to another
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Why Sho= uld We Care?
nOur app= roach allows for the streamlined design and creation of molecu= lar devices that interact with light
nSome Examples:
<= span class=3DB1B style=3D'position:absolute;left:-4.01%;top:.49em'>nSolar cells
<= span class=3DB1B style=3D'position:absolute;left:-4.01%;top:.49em'>nMole= cular wire initiators/acceptors
<= span class=3DB1B style=3D'position:absolute;left:-4.01%;top:.49em'>nLigh= t-reactive material
<= span class=3DB1B style=3D'position:absolute;left:-4.01%;top:.49em'>nMole= cular photonic computers…
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Our Cur= rent Work
nThree new “building blocks” are being examined in our group:
nFullerene / TM systems
nLinear multimetallic systems
nTungsten isocyanide complexes
nGot any ideas?
nSpectroscopic instrument testing and development
nDendrimer Modification for BBB Transfer
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050202 SAACS Mtg
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Fullerenes and Transition Metals
nWhy should we put t= hem together?
<= span style=3D'font-size:85%'>nFullerenes can be reduced multiple times but are insoluble
<= span style=3D'font-size:85%'>nTransition metal c= omplex could enhance fullerene solubility
nTry different tran= sition metals to easily change the system
<= span style=3D'font-size:90%'>nCurrent ligands that connect the transition metal core and fullerene lack rigidity and conjugation
<= span style=3D'font-size:85%'>nLittle direct elec= tronic communication between the transition metal and the fullerene
n
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050202 SAACS Mtg
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What We’re Doing
nAttach a “handle” to the fullerene that can b= e used to build a rigid structure
Joel Deye
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050202 SAACS Mtg
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What We’re Doing Now and Soon
James Kareth
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050202 SAACS Mtg
10
What We’re Doing Soon
<= ![endif]>
0
Celeste Morris
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050202 SAACS Mtg
11
Linear Multimetallic Systems
nMany researchers currently investigate the interaction of conjugated polymers with pendant TM complexes
<= span class=3DB1B style=3D'position:absolute;left:-3.5%;top:.49em'>nAllow= for the tweaking of the polymer properties by changing the TM system&#= 13;
<= span class=3DB1B style=3D'position:absolute;left:-3.44%;top:.49em'>nTM c= omplex doesn’t affect the polymer properties as much as hoped
n
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050202 SAACS Mtg
12
A Different Approach
nUtilize a tethered phenanthroline ligand to = wrap around the TM
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050202 SAACS Mtg
13
Here’s One Way to Do It…
Sarah (Beetem) Nelson
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